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The heat capacity of liquid carbon disulfide + acetonitrile, especially near the upper critical solution temperature

Govindarajan, K and Viswanathan, B and Gopal, ESR (1973) The heat capacity of liquid carbon disulfide + acetonitrile, especially near the upper critical solution temperature. In: The Journal of Chemical Thermodynamics, 5 (1). pp. 73-81.

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Abstract

The heat capacity Cp of the binary liquid system CS2 + CH3CN has been studied. This system has an upper critical solution temperature To ≈ 323.4 K and a critical mole fraction of CS2xo ≈ 0.5920. Measurements were made both for mixtures close to and far away from the critical region. The heat capacity of the mixture with x = xo exhibits a symmetric logarithmic anomaly around Tc, which is apparently preserved even for compositions in the immediate vicinity of xc. For compositions far away from xc, only a normal rise in Cp over the covered temperature range is observed.

Item Type: Journal Article
Additional Information: Copy right of this article belongs to Elsevier Science.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 09 Jan 2010 09:18
Last Modified: 19 Sep 2010 05:48
URI: http://eprints.iisc.ernet.in/id/eprint/23943

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