Verneker, VR Pai and Sharma, A Nagaraja and Jain, SR (1976) Thermal Decomposition of hydrazinium monoperchlorate in the solid state. In: Thermochimica Acta, 17 (3). pp. 319-323.
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Abstract
Hydrazinium monoperchlorate (HP-1) has been shown to decompose thermally in the solid state according to the chemical equation: 5N2H5CIO4 = 4NH4CIO4+1HCI+3N2+4H2O The activation energy for the evolution of HCl as determined mass spectrometrically is 8.05 kcal mol−1 in the temperature range of 80 to 120°C. The rate of decomposition is seen to be altered by doping HP-1 with small concentrations of SO2−4, Ca2+ and Al3+.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 11 Dec 2009 08:37 |
| Last Modified: | 19 Sep 2010 05:48 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/23955 |
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