Verneker, VR Pai and Sharma, A Nagaraja and Jain, SR (1976) Thermal Decomposition of hydrazinium monoperchlorate in the solid state. In: Thermochimica Acta, 17 (3). pp. 319-323.
article2.pdf - Published Version
Restricted to Registered users only
Download (286Kb) | Request a copy
Hydrazinium monoperchlorate (HP-1) has been shown to decompose thermally in the solid state according to the chemical equation: 5N2H5CIO4 = 4NH4CIO4+1HCI+3N2+4H2O The activation energy for the evolution of HCl as determined mass spectrometrically is 8.05 kcal mol−1 in the temperature range of 80 to 120°C. The rate of decomposition is seen to be altered by doping HP-1 with small concentrations of SO2−4, Ca2+ and Al3+.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||11 Dec 2009 08:37|
|Last Modified:||19 Sep 2010 05:48|
Actions (login required)