Padma, DK and Vijayalakshmi, SK and Vasudevamurthy, AR (1976) Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride. In: Journal of Fluorine Chemistry, 8 (6). pp. 461-465.
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Pure thiophosphoryl fluoride has been prepared by the fluorination of thiophosphoryl chloride by sodium fluoride in acetonitrile medium. Oxidation of this phosphoryl fluoride by acidified chloramine-T ruptures the phosphorus-sulphur bond and oxidises the sulphur present to the hexavalent state. Anhydrous hydrogen iodide reduces the sulphur to hydrogen sulphide and phosphorus to the trivalent state.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||11 Dec 2009 07:33|
|Last Modified:||19 Sep 2010 05:48|
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