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Bromination of Intermolecular Chelate Linkage Isomers of 3-Oximino-4,9-Dimethyl (or 4,7,9-Trimethyl)-5,8-Diazadodeca-4,8-Diene-2,11-Dionato Nickel(II)

Dixit, NS and Patel, CC (1976) Bromination of Intermolecular Chelate Linkage Isomers of 3-Oximino-4,9-Dimethyl (or 4,7,9-Trimethyl)-5,8-Diazadodeca-4,8-Diene-2,11-Dionato Nickel(II). In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 6 (4). pp. 265-273.

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Abstract

The reaction of the title complexes (FIG. 1) with N-bromosuccinimide or bromine in chloroform yields isomeric bromo complexes on substitution of the γ-CH carbon proton by bromine. The brominated products have been characterised by ir, pmr, electronic absorption spectra, conductivity and magnetic susceptibility measurements. The linkage isomerisation of the brominated products in chloroform has been shown to depend on the diamine residue.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 23 Oct 2009 09:28
Last Modified: 23 Oct 2009 09:28
URI: http://eprints.iisc.ernet.in/id/eprint/24195

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