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Effect of pretreatment on the sublimation of ammonium perchlorate

Verneker, Vencatesh R. Pai and Kishore, Kaushal and Kannan, Malayan P (1977) Effect of pretreatment on the sublimation of ammonium perchlorate. In: Journal of Applied Chemistry and Biotechnology, 27 (1). pp. 309-317.

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Official URL: http://www3.interscience.wiley.com/journal/1142215...

Abstract

The effects of pretreatments on the sublimation of pure ammonium perchlorate (AP) were studied by differential thermal analysis. The addition of inorganic salts (doping), or preheating, lead to desensitisation of the sublimation process, whereas it was sensitised by precompression. Sublimation increased with decrease in the particle size of the AP from 500 to 200 microns, but decreased with a further decrease in size from 200 to 100 microns. The results are interpreted in terms of gross imperfections and strain in the AP crystals.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Wiley.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 20 Jan 2010 10:38
Last Modified: 20 Jan 2010 10:38
URI: http://eprints.iisc.ernet.in/id/eprint/24440

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