Sudhir, Sai V and Baig, Nasir Baig Rashid and Chandrasekaran, Srinivasan (2009) Convenient Synthesis of Ferrocene Conjugates Mediated by Benzyltriethylammonium Tetrathiomolybdate in a Multi-Step Tandem Process. In: European Journal of Organic Chemistry (31). pp. 5365-5372.
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The synthesis of a wide range of ferrocene-derived sulfur-linked mono- and disubstituted Michael adducts and conjugates mediated by benzyltriethylammonium tetrathiomolybdate (1) in a tandem process is reported. New route to access acryloylferrocene (4) and 1,1'-diacryloylferrocene (5) is discussed. Conjugation of amino acids to ferrocene is established via their N and C termini and also via side chains employing conjugate addition as key step to furnish mono-and divalent conjugates. This methodology has also been extended to access several ferrocene-carbohydrate conjugates. The electrochemical behavior of some selected ferrocene conjugates was studied by cyclic voltammetry.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Wiley.|
|Keywords:||Sandwich complexes; Ferrocene conjugates; Cyclic voltammetry; Amino acids; Carbohydrates|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||01 Dec 2009 06:08|
|Last Modified:||01 Aug 2011 12:20|
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