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Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source

Maddani, Mahagundappa R and Moorthy, Saravana K and Prabhu, Kandikere R (2010) Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source. In: Tetrahedron, 66 (1). pp. 329-333.

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Abstract

A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2](2)) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier science.
Keywords: Catalytic reduction; Chemoselectivity; Amines; Molybdenum; Silanes
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 19 Jan 2010 09:05
Last Modified: 19 Sep 2010 05:54
URI: http://eprints.iisc.ernet.in/id/eprint/25413

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