Maddani, Mahagundappa R and Moorthy, Saravana K and Prabhu, Kandikere R (2010) Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source. In: Tetrahedron, 66 (1). pp. 329-333.
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Abstract
A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2](2)) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright for this article belongs to Elsevier science. |
| Keywords: | Catalytic reduction; Chemoselectivity; Amines; Molybdenum; Silanes |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 19 Jan 2010 09:05 |
| Last Modified: | 19 Sep 2010 05:54 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/25413 |
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