Rao, Ch Pulla and Balaram, Padmanabhan and Rao, CNR (1980) 13C nuclear magnetic resonance studies of the binding of alkali and alkaline earth metal salts to amides. In: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 76 . pp. 1008-1013.
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3C resonances of carbonyl and methyl groups in amides are shifted down-field on interaction with alkali and alkaline earth metal salts. The magnitude of the shift depends on the ionic potential of the cation. Ions like Li+ bind to the amide carbonyl group both in neat amide solutions as well as in concentrated salt solutions in water.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Royal Society of chemistry.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||22 Feb 2010 09:52|
|Last Modified:||19 Sep 2010 05:55|
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