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A stereoselective total synthesis of (−)-seychellene

Srikrishna, A and Ravi, G (2008) A stereoselective total synthesis of (−)-seychellene. In: Tetrahedron Letters, 64 (11). pp. 2565-2571.

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Abstract

A stereoselective total synthesis of the tricyclic sesquiterpene (−)-seychellene, starting from (R)-carvone via (R)-3-methylcarvone has been accomplished, employing a combination of intermolecular Michael addition–intramolecular Michael addition sequence, a stereoselective hydrogenation, and an intramolecular alkylation reaction.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Seychellene;Sesquiterpene synthesis;Intramolecular alkylation;Carvone;Double Michael reaction.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Mar 2010 10:53
Last Modified: 19 Sep 2010 05:56
URI: http://eprints.iisc.ernet.in/id/eprint/25936

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