Mondal, TK and Raghavaiah, P and Patra, AK and Sinha, C (2010) Ru(II)-CO complexes of thioarylazoimidazoles: Syntheses, structures, spectroscopy and DFT calculation. In: Inorganic Chemistry Communications, 13 (2). pp. 273-277.
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Abstract
The complexes, cis-(CO)-trans-(Cl)-[Ru(SRaaiNR)(CO)(2)Cl-2] (2) and trans-(Cl)-[Ru(SRaaiNR)(CO)Cl-2] (3) (SRaaiNR = 1-alkyl-2-{(o-thioalkyl)phenylazo}imidazoles; R = Me (1a) and Et (1b)) have been synthesized and characterized. The structural confirmation is achieved by single crystal X-ray structure determinations. The complexes show Ru(III)/Ru(II) couple and ligand reductions. Electronic structure and spectral properties of the complexes have been explained with the DFT and TDDFT calculation. (C) 2009 Elsevier B.V. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Ruthenium-carbonyl; Thioarylazoimidazoles; X-ray structure; Electrochemistry; DFT calculation |
| Department/Centre: | Others |
| Date Deposited: | 30 Mar 2010 10:54 |
| Last Modified: | 19 Sep 2010 05:57 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/26241 |
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