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In Situ Cryocrystallization of Diphenyl Ether: C-H...\pi Mediated Polymorphic Forms

Choudhury, Angshuman R and Islam, Kabirul and Kirchner, Michael T and Mehta, Goverdhan and Row, Tayur Guru N (2004) In Situ Cryocrystallization of Diphenyl Ether: C-H...\pi Mediated Polymorphic Forms. In: Journal of the American Chemical Society, 126 (39). pp. 12274-12275.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja046134k

Abstract

Polymorphism in diphenyl ether has been identified during in situ crystallization via single-crystal X-ray diffraction. Only weak inter- and intramolecular C-H...\pi interactions control the packing of the molecules in both crystal forms monoclinic centrosymmetric $(P2_1/n)$ in form I and orthorhombic noncentrosymmetric $(P2_12_12_1)$ in form II.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 Feb 2007
Last Modified: 19 Jan 2012 04:51
URI: http://eprints.iisc.ernet.in/id/eprint/2648

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