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Thiabowls: Synthesis, Molecular Structure, and Novel Supramolecular Architecture of Trithia-[3]-Peristylane

Mehta, Goverdhan and Gagliardini, Vanessa and Schaefer, Carsten and Gleiter, Rolf (2004) Thiabowls: Synthesis, Molecular Structure, and Novel Supramolecular Architecture of Trithia-[3]-Peristylane. In: Organic Letters, 6 (10). pp. 1617-1620.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol049507v

Abstract

A synthesis of trithia-[3]-peristylane, $C_6H_6S_3$, a novel $C_3_v$ symmetric thiabowl, from the exotic hydrocarbon bullvalene has been accomplished. The X-ray crystal structure of this trithiabowl displays an unprecedented supramolecular architecture in the solid state with 12 CH...S interactions involving all of its six hydrogen atoms and the two lone pairs on each of the three sulfur atoms.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 18 Jan 2005
Last Modified: 18 Jan 2012 10:07
URI: http://eprints.iisc.ernet.in/id/eprint/2652

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