Srikrishna, A and Ramachary, DB (2005) Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 44 (4). pp. 751-761.Full text not available from this repository. (Request a copy)
Synthetic approach to 3-alkoxythapsane, comprising of the carbon framework of a small group of sesquiterpenes containing three contiguous quaternary carbon atoms has been described. A combination of alkylation, orthoester Claisen rearrangement and intramolecular diazoketone cyclopropanation has been employed for the creation of the three requisite contiguous quaternary carbon atoms.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to National Institute of Science Communication and Information Resources.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||09 Jun 2010 04:47|
|Last Modified:||09 Jun 2010 04:47|
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