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Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene

Srikrishna, A and Ramachary, DB (2005) Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 44 (4). pp. 751-761.

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Official URL: http://www3.interscience.wiley.com/journal/1105743...

Abstract

Synthetic approach to 3-alkoxythapsane, comprising of the carbon framework of a small group of sesquiterpenes containing three contiguous quaternary carbon atoms has been described. A combination of alkylation, orthoester Claisen rearrangement and intramolecular diazoketone cyclopropanation has been employed for the creation of the three requisite contiguous quaternary carbon atoms.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 09 Jun 2010 04:47
Last Modified: 09 Jun 2010 04:47
URI: http://eprints.iisc.ernet.in/id/eprint/27218

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