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Correlation of thermodynamic properties of chloromethanes

Seshadri, DN and Viswanath, Dabir S and Kuloor, Narasing R (1969) Correlation of thermodynamic properties of chloromethanes. In: Journal of Chemical & Engineering Data, 14 (3). pp. 322-328.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/je60042a031

Abstract

A correlation for entropy and enthalpy based on the two-parameter law of corresponding states and the reference substance concept has been obtained. For 199 points tested, the over-all average absolute deviation and the maximum deviations in the calculated values of entropy with the available data are 0.74 and 7.20%. The corresponding deviations of enthalpy are 1.86 and 15.0%, respectively. A compressibility chart for chloromethanes has been made and shown to be superior to existing charts. For 102 points tested, the average absolute and maximum deviations in the compressibilities were 1.80 and 19.5%, respectively.

Item Type: Journal Article
Additional Information: Copy right of this article belongs to American Chemical Society.
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 18 May 2010 06:02
Last Modified: 19 Sep 2010 06:05
URI: http://eprints.iisc.ernet.in/id/eprint/27606

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