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Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity

Muthusamy, Sengodagounder and Krishnamurthi, Janagiraman and Nethaji, Munirathnam (2005) Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity. In: Chemical Communications (30). pp. 3862-3864.

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Abstract

The reverse regio- and diastereoselectivities are observed between the reactions involving 5- and 6-membered-ring cyclic carbonyl ylide dipoles with alpha-methylene ketones. A mild catalytic route to synthesize spirocyclic systems with high regio-, chemo- and diastereoselectivities is described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 04 Jun 2010 06:52
Last Modified: 19 Sep 2010 06:05
URI: http://eprints.iisc.ernet.in/id/eprint/27609

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