Muthusamy, Sengodagounder and Krishnamurthi, Janagiraman and Nethaji, Munirathnam (2005) Highly regio-, chemo- and diastereoselective synthesis of oxa-bridged spirocycles: A novel observation of reverse selectivity. In: Chemical Communications (30). pp. 3862-3864.
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The reverse regio- and diastereoselectivities are observed between the reactions involving 5- and 6-membered-ring cyclic carbonyl ylide dipoles with alpha-methylene ketones. A mild catalytic route to synthesize spirocyclic systems with high regio-, chemo- and diastereoselectivities is described.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal Society of Chemistry.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||04 Jun 2010 06:52|
|Last Modified:||19 Sep 2010 06:05|
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