Warrier, AVR and Narayanan, PS (1967) Infra-red spectra of crystalline chloroacetates of Cu, Ca, Sr, Ba and Pb. In: Spectrochimica Acta Part A: Molecular Spectroscopy, 23 (4). pp. 1061-1067.
23.pdf - Published Version
Restricted to Registered users only
Download (267Kb) | Request a copy
The infra-red spectra of Cu, Ca, Sr, Ba and Pb chloroacetates were studied in order to investigate the effect of co-ordination on the vibration spectra of the ligand. The shifts of the symmetric and antisymmetric COO− vibrational frequencies indicate a bridged structure as the most probable one for the complexes investigated. No linear relationship between the shifts of the COO− stretching frequencies and E/r (where E is the electron excitation energy and r the ionic radius) was observed. No systematic mass effect on these COO− frequencies also could be established.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Physical & Mathematical Sciences > Physics|
|Date Deposited:||14 May 2010 03:57|
|Last Modified:||19 Sep 2010 06:06|
Actions (login required)