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Oxalato complexes of oxovanadium (IV)

Sathyanarayana, DN and Patel, CC (1966) Oxalato complexes of oxovanadium (IV). In: Journal of Inorganic and Nuclear Chemistry, 28 (10). pp. 2277-2283.

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Official URL: http://dx.doi.org/10.1016/0022-1902(66)80117-3

Abstract

Oxalato oxovanadium (IV) complexes with neutral ligand molecules like dimethyl sulphoxide (DMSO) and antipyrine (Apy), VOOX·2DMSO and VOOX·2Apy and complex oxalates of oxovanadium (IV)-(NH4)2[VOOX2]·2H2O, (NH4)2[(VO)2OX3]·6H2O and (NH4)2[(VO)2OX3] have been prepared and characterized by different methods. In the divanadyl complexes, V-V and V-O-V-O types of bonding are shown to be absent by magnetic and spectral data and a bridged oxalato group co-ordinated to the two vanadium atoms is shown to be present, in addition to the usual bidentate oxalate groups. The possible stereochemical arrangements are indicated for the complexes.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 17 May 2010 09:59
Last Modified: 19 Sep 2010 06:06
URI: http://eprints.iisc.ernet.in/id/eprint/27876

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