ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Charge distribution, dipole moment and molecular structure of silyl compounds

Krishnamurthy, VN and Soundararajan, S (1965) Charge distribution, dipole moment and molecular structure of silyl compounds. In: Journal of Inorganic and Nuclear Chemistry, 27 (11). pp. 2341-2344.

[img] PDF
13.pdf - Published Version
Restricted to Registered users only

Download (224Kb) | Request a copy
Official URL: http://dx.doi.org/10.1016/0022-1902(65)80125-7

Abstract

The formal charge distribution and hence the electric moments of a number of halosilanes and their methyl derivatives have been calculated by the method of Image and Image . The difference between the observed and the calculated values in simple halosilanes is attributed to a change in the hybridization of the terminal halogen atom and in methyl halosilanes to the enhanced electron release of the methyl group towards silicon compared with carbon.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 May 2010 06:14
Last Modified: 19 Sep 2010 06:07
URI: http://eprints.iisc.ernet.in/id/eprint/27921

Actions (login required)

View Item View Item