Krishnamurthy, VN and Soundararajan, S (1965) Charge distribution, dipole moment and molecular structure of silyl compounds. In: Journal of Inorganic and Nuclear Chemistry, 27 (11). pp. 2341-2344.
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The formal charge distribution and hence the electric moments of a number of halosilanes and their methyl derivatives have been calculated by the method of Image and Image . The difference between the observed and the calculated values in simple halosilanes is attributed to a change in the hybridization of the terminal halogen atom and in methyl halosilanes to the enhanced electron release of the methyl group towards silicon compared with carbon.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||19 May 2010 06:14|
|Last Modified:||19 Sep 2010 06:07|
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