Nayak, Ramdas U and Santhanakrishnan, TS and Dev, Sukh (1963) Studies in sesquiterpenes-XX. Acetoxymethylation of longifolene. In: Tetrahedron, 19 (12). pp. 2281-2292.
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Longifolene in Prins reaction with formaldehyde yielded the expected ω-acetoxymethyl longifolene, which was transformed into a number of interesting derivatives. Configuration of the Prins product has been arrived at by NMR measurements. The UV absorption of these derivatives show a considerable bathochromic shift with respect to those in the camphene series and this could be attributed to the slight twisting of the ethylenic linkage in longifolene and its derivatives.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||25 May 2010 06:38|
|Last Modified:||19 Sep 2010 06:07|
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