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Raman spectrum of triglycine selenate (G3Se), [(NH2CH2COOH)3 H2SeO4]

Balasubramanian, K and Krishnan, RS (1963) Raman spectrum of triglycine selenate (G3Se), [(NH2CH2COOH)3 H2SeO4]. In: Proceedings of the Indian Academy of Sciences - Section A, 58 (4). pp. 209-215.

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Abstract

The Raman spectrum of a single crystal of triglycine selenate G3Se which is ferroelectric below 22° C. has been photographed using λ 2537 excitation. 42 Raman lines have been recorded of which 6 belong to the lattice spectrum, 3 are due to NH...O oscillations and the remaining 33 are due to internal oscillations of the ions of glycine and SeO4--. There is a close similarity between the spectrum of triglycine selenate and the spectrum of its isomorph, triglycine sulphate, the frequency shifts due to the SO4-- ion being replaced by the frequency shifts due to the SeO4-- ion. The existence of glycine in the zwitterion form in the structure of G3Se is substantiated by the appearance in the Raman spectrum of lines which are attributable to NH3+ groups and COO- groups. The appearance of the additional C-H line at 2982 cm.-1 in the spectrum of triglycine selenate which is absent in the spectrum of α-glycine indicates the existence of planar monoprotonated glycine also in the structure, as indicated by X-ray studies.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 02 Jun 2010 09:22
Last Modified: 19 Sep 2010 06:08
URI: http://eprints.iisc.ernet.in/id/eprint/28188

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