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Nature, stability and bonding of the peroxy group in peroxy titanium compounds

Patel, CC and Jere, GV (1963) Nature, stability and bonding of the peroxy group in peroxy titanium compounds. In: Journal of Inorganic and Nuclear Chemistry, 25 (9). pp. 1155-1159.

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Official URL: http://dx.doi.org/10.1016/0022-1902(63)80137-2

Abstract

Some physicochemical properties of peroxy titanium compounds are explained by assigning a strained triangular ring structure to the peroxy titanyl group, with a bent and reduced overlap of the O---O bonding orbitals. The stability of the peroxy group is found to depend on the stability of the other ligands. The decreasing order of stability of the peroxy group in the compounds is as: oxalato > meleato > malonato > sulphato > peroxide of titanium.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 02 Jun 2010 09:29
Last Modified: 19 Sep 2010 06:08
URI: http://eprints.iisc.ernet.in/id/eprint/28191

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