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Hydrolytic reactions of tetrasulphur tetranitride in a homogeneous medium

Nair, CGR and Murthy, ARV (1963) Hydrolytic reactions of tetrasulphur tetranitride in a homogeneous medium. In: Journal of Inorganic and Nuclear Chemistry, 25 (4). pp. 453-459.

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Official URL: http://dx.doi.org/10.1016/0022-1902(63)80196-7

Abstract

The hydrolytic reactions of tetrasulphur tetranitride are studied in a homogeneous medium. Alkaline hydrolysis gives sulphite, thiosulphate, sulphate and sulphide whereas the products in acid hydrolysis are mainly sulphur dioxide, elemental sulphur and hydrogen sulphide, with traces of polythionates. Under optimum conditions, tetrasulphur tetranitride reacts with sulphite consuming 2 moles of sulphite per mole of sulphur nitride to give 2 moles of trithionate. The reaction of sulphur nitride with thiosulphuric acid gives pentathionate and tetrathionate.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 23 Jun 2010 10:00
Last Modified: 19 Sep 2010 06:08
URI: http://eprints.iisc.ernet.in/id/eprint/28220

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