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Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes

Addy, DA and Pierce, GA and Vidovic, D and Mallick, D and Jemmis, ED and Goicoechea, JM and Aldridge, S (2010) Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes. In: Journal of the American Chemical Society, 132 (13). pp. 4586-4588.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja101192e

Abstract

Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 14 Jul 2010 05:28
Last Modified: 29 Feb 2012 05:36
URI: http://eprints.iisc.ernet.in/id/eprint/28931

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