Addy, DA and Pierce, GA and Vidovic, D and Mallick, D and Jemmis, ED and Goicoechea, JM and Aldridge, S (2010) Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes. In: Journal of the American Chemical Society, 132 (13). pp. 4586-4588.
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Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to American Chemical Society.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||14 Jul 2010 05:28|
|Last Modified:||29 Feb 2012 05:36|
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