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Quinone Studies—II : Reduction potentials of some 3-substituted phenanthrene quinones

Bhatt, MV and Narayanankutty, N (1972) Quinone Studies—II : Reduction potentials of some 3-substituted phenanthrene quinones. In: Tetrahedron, 28 (16). pp. 4325-4331.

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Official URL: http://dx.doi.org/10.1016/S0040-4020(01)88955-9

Abstract

Polarographic reduction potentials of seven 3-substituted phenanthrenequinones have been determined in aqueous dioxan and aqueous ethanol under different pH conditions. The substituent effects on the reduction potentials could be correlated with the Hammett σ- constants (correlation coefficients> 0·995). The possibility of using reduction potentials as an accurate measure of resonance energy has been pointed out.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 12 Jul 2010 09:29
Last Modified: 19 Sep 2010 06:11
URI: http://eprints.iisc.ernet.in/id/eprint/29179

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