ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Chemistry of Tetrathiomolybdate and Tetraselenotungstate: Applications in Carbohydrate Chemistry

Sridhar, Perali Ramu and Saravanan, V and Chandrasekaran, S (2005) Chemistry of Tetrathiomolybdate and Tetraselenotungstate: Applications in Carbohydrate Chemistry. In: Pure and Applied Chemistry, 77 (1). pp. 145-153.

[img] PDF
Chemistry.pdf - Published Version
Restricted to Registered users only

Download (290Kb) | Request a copy
Official URL: http://iupac.org/publications/pac/77/1/0145/

Abstract

An efficient one pot synthesis of thio and selenolevoglucosans from 1,6-diactivated carbohydrate derivatives has been achieved using benzyltriethylammonium tetrathiomolybdate, $[BnNEt_3]_2MoS_4$, as a sulfur transfer reagent and tetraethylammonium tetraselenotungstate, $[Et_4N]_2WSe_4$, as a selenium transfer reagent, respectively. The methodology has also been extended to the synthesis of 1,5-epithio and 1,5-episeleno pentoses.

Item Type: Journal Article
Additional Information: The copyright for this article belongs to International Union of Pure and Applied Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Apr 2005
Last Modified: 20 Jan 2012 09:17
URI: http://eprints.iisc.ernet.in/id/eprint/3021

Actions (login required)

View Item View Item