ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

An environment-friendly Beckmann rearrangement: the diazotisation of ketoxime carbamates

Anilkumar, R and Chandrasekhar, Sosale (2000) An environment-friendly Beckmann rearrangement: the diazotisation of ketoxime carbamates. In: Tetrahedron Letters, 41 (37). pp. 7235-7237.

[img] PDF
carba.pdf - Published Version
Restricted to Registered users only

Download (123Kb) | Request a copy
Official URL: http://dx.doi.org/10.1016/S0040-4039(00)01243-0

Abstract

The titled reaction was effected with iso-amyl nitrite or sodium nitrite, both in cone. H2SO4 at 0-25 degrees C in excellent yields (55-98%). Apart from the mild temperatures employed, organic solvents and reagents can be avoided, and the by-products are CO2 and N-2, so the conditions are environment-friendly. (C) 2000 Elsevier Science Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Aug 2010 10:27
Last Modified: 19 Sep 2010 06:13
URI: http://eprints.iisc.ernet.in/id/eprint/31123

Actions (login required)

View Item View Item