Subramanian, N and Raman, KV (1989) NQR study of complexes between p-dichlorobenzene and some aromatic π acceptors. In: Journal of Molecular Structure, 197 . pp. 53-57.
nqr.pdf - Published Version
Restricted to Registered users only
Download (172Kb) | Request a copy
The charge-transfer complexes of p-dichlorobenzene (PDB) with some aromatic π acceptors such as m-nitrobenzaldehyde (MNB), picric acid (PA), p-nitrobenzoic acid (PNB), and m-dinitrobenzene (MDNB) were prepared by slowly adding the acceptor to the molten donor and then cooling the mass to 15°C. The NQR frequencies of these complexes were measured at room temperature. Contrary to the theoretical prediction, the NQR shift is positive, indicating that the NQR shift in donor-acceptor complexes is indirectly related to the charge-transfer interaction. Bond properties are discussed in terms of frequency shift.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Physical & Mathematical Sciences > Physics|
|Date Deposited:||10 Aug 2010 10:50|
|Last Modified:||19 Sep 2010 06:13|
Actions (login required)