Competing magnetic interactions in a dinuclear Ni(II) complex: Antiferromagnetic O-H center dot center dot center dot O moiety and ferromagnetic N-3(-) ligand

Sarkar, Sumana and Datta, Ayan and Mondal, Amrita and Chopra, Deepak and Ribas, Joan and Rajak, Kajal Krishna and Sairam, Sairam M and Pati, Swapan K (2006) Competing magnetic interactions in a dinuclear Ni(II) complex: Antiferromagnetic O-H center dot center dot center dot O moiety and ferromagnetic N-3(-) ligand. In: Journal of Physical Chemistry B, 110 (1). pp. 12-15.

PDF jp0556963.pdf - Published Version Restricted to Registered users only Download (73Kb) | Request a copy

Abstract

Synthesis, structural characteristics, magnetic studies and DFT calculations in Ni(II) dinuclear complexes containing two bridging N-3(-) and an O-(HO)-O-... linkage reveal the existence of ferromagnetic interactions between Ni(II) centers via N-3(-) ligands and antiferromagnetic interactions through the H-bonded moiety. The overall magnetic behavior of the system depends on the delicate balance between these two competing interactions.

Item Type:	Journal Article
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	08 Sep 2010 09:44
Last Modified:	19 Sep 2010 06:15
URI:	http://eprints.iisc.ernet.in/id/eprint/31912

Actions (login required)

View Item