Gopinath, Purushothaman and Debasree, Chanda and Vidyarini, Ravindran Sasitha and Chandrasekaran, Srinivasan (2010) Synthesis of S-functionalized thioesters using thioaroylate ions derived from carboxylic acids and tetrathiomolybdate via acyloxyphosphonium intermediates. In: Tetrahedron, 66 (34). pp. 7001-7011.
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Thioaroylate ions generated in situ from acyloxyphosphonium salts and tetrathiomolybdate upon Michael addition or ring opening of three membered systems led to a facile synthesis of S-funcationalized thioesters. While the ring opening of aziridines gave very good yield of the products, Micheal addition and epoxide ring opening gave moderate yields.(C) 2010 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Keywords:||Carboxylic acids;Michael addition; Ring opening; Sulfur; Molybdenum.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||08 Sep 2010 07:10|
|Last Modified:||19 Sep 2010 06:15|
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