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A Pd-6 Molecular Cage via Multicomponent Self-Assembly Incorporating Both Neutral and Anionic Linkers

Bar, Arun Kumar and Mostafa, Golam and Mukherjee, Partha Sarathi (2010) A Pd-6 Molecular Cage via Multicomponent Self-Assembly Incorporating Both Neutral and Anionic Linkers. In: Inorganic Chemistry, 49 (17). pp. 7647-7649.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic101139s

Abstract

A Pd-6 molecular cage [{(tmen)Pd}(6)(bpy)(3)(tma)2)](NO3)(6) [1; where tmen = N,N,N,N-tetramethylethylene diamine, bpy = 4,4'-bipyridyl,and H(3)tma = trimesic acid] was prepared via the template-free three-component seff-assembly of a cis-blocked palladium(II) acceptorin combination with a tricarboxylate and a dipyridyl donor. Complex 1 represents the first example of a 3D palladium(II) cage of defined shape incorporating anionic and neutral linkers. Guest-induced exclusive formation of this cage was also monitored by an NMR study.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 15 Sep 2010 09:32
Last Modified: 19 Sep 2010 06:16
URI: http://eprints.iisc.ernet.in/id/eprint/32139

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