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Inclusion of Ferrocene in a Cyclodextrin-Functionalized Layered Metal Hydroxide: A New Organometallic-Organic-LDH Nanohybrid

Mohanambe, L and Vasudevan, S (2005) Inclusion of Ferrocene in a Cyclodextrin-Functionalized Layered Metal Hydroxide: A New Organometallic-Organic-LDH Nanohybrid. In: Inorganic Chemistry, 44 (7). pp. 2128-2130.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic050039a

Abstract

Cyclodextrin cavities have been grafted into a layered metal hydroxide to create hydrophobic nanopockets within the galleries of the inorganic solid. Neutral ferrocene molecules can be included within the grafted cavities by partitioning from a polar solvent to generate a new organometallic-organic-inorganic hybrid. The included ferrocene has been characterized by electronic and Raman spectroscopy. The capability of the cyclodextrin-functionalized solid to separate hydrophobic and hydrophilic derivatives of ferrocene is demonstrated.

Item Type: Journal Article
Additional Information: The copyright for this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 May 2005
Last Modified: 25 Jan 2012 05:57
URI: http://eprints.iisc.ernet.in/id/eprint/3222

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