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Low-temperature synthesis of novel layered alkali metal-MoO3 bronzes and hexagonal bronzes of the type KyW1−xMoxO3

Ganguli, AK and Ganapathi, L and Gopalakrishnan, J and Rao, CNR (1988) Low-temperature synthesis of novel layered alkali metal-MoO3 bronzes and hexagonal bronzes of the type KyW1−xMoxO3. In: Journal of Solid State Chemistry, 74 (1). pp. 228-231.

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Official URL: http://dx.doi.org/10.1016/0022-4596(88)90349-0

Abstract

A new class of layered alkali metal-MoO3 bronzes,AxMoO3 (A =Li, Na, K, Rb), with nearly the same unit cell parameters as the host oxide has been synthesized by the solid-state reaction of MoO3 with alkali metal iodides around 575 K; LixMoO3 absorbs H2O causing an increase in theb parameter of the unit cell. Hexagonal potassium bronzes of W1−xMoxO3 are synthesized for the first time.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 23 Sep 2010 09:27
Last Modified: 23 Sep 2010 09:27
URI: http://eprints.iisc.ernet.in/id/eprint/32355

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