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A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide

Chandrasekhar, Sosale and Sridhar, Malayalam (2000) A bifunctional approach towards the mild oxidation of organic halides: 2-dimethylamino-N,N-dimethylaniline N-oxide. In: Tetrahedron Letters, 41 (28). 5423-5425 .

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Official URL: http://dx.doi.org/10.1016/S0040-4039(00)00874-1

Abstract

The titled reagent incorporates an oxygen-centred nucleophile and a basic moiety�in a suitably mutual orientation�in the same molecule. It oxidises various primary benzylic bromides to the corresponding aromatic aldehydes under relatively mild conditions (MeCN/rt�50°C/6�24 h) in high yields (83�97%), and is thus a useful alternative to the Kornblum procedure.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 30 Sep 2010 10:05
Last Modified: 30 Sep 2010 10:05
URI: http://eprints.iisc.ernet.in/id/eprint/32538

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