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Open-framework mixed aliphatic dicarboxylates of lanthanum

Dan, Meenakshi and Cottereau, G and Rao, CNR (2005) Open-framework mixed aliphatic dicarboxylates of lanthanum. In: Solid State Sciences, 7 (4). pp. 437-443.

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Abstract

A lanthanum mixed dicarboxylate of the formula $[La_{2}(C_{2}O_{4})_{2}(C_{6}H_{8}O_{4})(H_{2}O)_{2}]$ containing metal oxalate layers connected by adipate and oxalate units has been synthesized hydrothermally. Hexagonal channels occur along the c-axis of this material. It has been possible to isolate another mixed dicarboxylate of the formula $[La_{2}(C_{2}O_{4})(C_{4}H_{4}O_{4})_{2}(H_{2}O)_{4}].4H_{2}O$ containing metal succinate layers connected by oxalate units.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 06 Jun 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3279

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