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Enantiospecific synthesis of tricyclo5.2.1.0(4,8)]decanes via acid catalysed rearrangement of isotwistanes

Srikrishna, A and Satyanarayana, G and Kumar, Pramod (2006) Enantiospecific synthesis of tricyclo5.2.1.0(4,8)]decanes via acid catalysed rearrangement of isotwistanes. In: Tetrahedron Letters, 47 (3). pp. 363-366.

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Official URL: http://dx.doi.org/10.1016/j.tetlet.2005.11.008

Abstract

An acid catalysed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo5.2.1.0(4.8)]-decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane. (c) 2005 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Molecular rearrangement; Isotwistanes; Pupukeananes; Allopupukeanane.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 20 Oct 2010 05:15
Last Modified: 20 Oct 2010 05:15
URI: http://eprints.iisc.ernet.in/id/eprint/32872

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