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The first enantioselective synthesis of (-)-microbiotol and(+)-\beta-microbiotene

Srikrishna, Adusumilli and Nagamani, Shankarnarayan A and Jagadeesh, Setti G (2005) The first enantioselective synthesis of (-)-microbiotol and(+)-\beta-microbiotene. In: Tetrahedron: Asymmetry, 16 (9). pp. 1569-1571.

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Abstract

The first enantioselective total synthesis of (-)-microbiotol and(+)-\beta-microbiotene, sesquiterpenes containing three neighboring quaternary carbon atoms belonging to the cyclocuparane group, starting from cyclogeraniol employing a Sharpless-Katsuki asymmetric epoxidation, a boron trifluoride etherate mediated epoxidere arrangement and an intramolecular diazo ketone cyclopropanation as key steps, is described.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 28 Jun 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3306

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