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Bis($\mu$-phenyl 2-pyridyl ketone $N^4$,$N^4$-butane-1,4-diylthiosemicarbazonato)bis[chlorocopper(II)]

Sreekanth, A and Suni, V and John, Rohith P and Nethaji, Munirathinam and Kurup, Prathapachandra MR (2005) Bis($\mu$-phenyl 2-pyridyl ketone $N^4$,$N^4$-butane-1,4-diylthiosemicarbazonato)bis[chlorocopper(II)]. In: Acta Crystallographica Section C-Crystal Structure Communications, 61 (Part 6). m284-m286.

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Abstract

The title compound, $[Cu_2(C_{17}H_{17}N_{4}S)_{2}C_{l2}]$, exhibits a dimeric structure related by a centre of symmetry. The monomers are linked to each other by the longest Cu-S apical distance observed to date among $Cu^{II}$ square-pyramidal complexes of $N^4$-substituted thiosemicarbazones. Each $Cu^{II}$ atom deviates from the coordination square plane, which contains the pyridyl and imine N atoms, the thiolate S atom and the $Cl^-$ anion, towards the S atom of the adjacent monomer. The dimers pack in a zigzag manner through the crystal.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Blackwell Publishing Inc.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 06 Jul 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3320

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