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A regio and stereospecific radical annulation route to chiral tricyclo[4.3.1.o3,7]decane (isotwistane) system1 synthesis of (+)-10-α-Naphthyl-5-epi-Pupukean-9-one

Srikrishna, A and Hemamalini, P and Sharma, Veera Raghava G (1991) A regio and stereospecific radical annulation route to chiral tricyclo[4.3.1.o3,7]decane (isotwistane) system1 synthesis of (+)-10-α-Naphthyl-5-epi-Pupukean-9-one. In: Tetrahedron Letters, 32 (45). pp. 6609-6610.

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Official URL: http://dx.doi.org/10.1016/0040-4039(91)80234-W

Abstract

Contrary to that of phenyl derivative 1 the radical 4 adds to radicophiles in an inter- followed by intra-molecular radical Michael addition (radical annulation), furnishing a novel route to chiral isotwistanes 5.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Keywords: Radical Cyclization;Annulation;Isotwistane;Pupukeanone.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 16 Nov 2010 06:37
Last Modified: 16 Nov 2010 06:37
URI: http://eprints.iisc.ernet.in/id/eprint/33698

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