Dwarakanath, K and Sathyanarayana, DN (1979) Vibrational Spectra and Normal Coordinate Analysis of N-Methyl Thiourea. In: Bulletin of the Chemical Society of Japan, 52 (7). pp. 2084-2087.
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The infrared spectra of N-methylthiourea (NMTU) and its N-deuterated and S-methylated species were measured. Assignment of the infrared and Raman spectra of NMTU has been accomplished by correlation with thiourea and by use of infrared band shifts on N-deuteration as well as S-methylation. Normal coordinate analysis was performed for all the fundamentals of NMTU and NMTU-d3, the assignments obtained from the force field calculations being discussed in relation to those in other related thioureas and thioamides. The potential barriers to the internal rotations for the ï¿½NH2, ï¿½CH3, and ï¿½CN groups were estimated from the force constants.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Chemical Society of Japan.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||28 Dec 2010 06:40|
|Last Modified:||28 Dec 2010 06:40|
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