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Vibrational analysis of 1,3-thiazolidine-2-thione and its selenium analogue

Devillanova, Francesco A and Devi, Gayathri KR and Sathyanarayana, DN and Verani, Gaetano (1979) Vibrational analysis of 1,3-thiazolidine-2-thione and its selenium analogue. In: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 35 (9). pp. 1083-1087.

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Official URL: http://dx.doi.org/10.1016/0584-8539(79)80007-0

Abstract

The i.r. spectra of 1,3-thiazolidine-2-thione, ?2-selone and their N-deuteriated derivatives have been investigated in the region between 4000 and 20 cm?1. A complete assignment of the fundamental vibrational frequencies has been made based upon the normal coordinate analysis carried out using a simple Urey�Bradley force field supplemented by the valence force constants for the out-of-plane vibrations of the planar molecular skeleton. The proposed assignments are discussed in relation to the group frequencies in structurally related molecules and in terms of the computed potential energy distributions among the symmetry coordinates.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 28 Dec 2010 06:30
Last Modified: 28 Dec 2010 06:30
URI: http://eprints.iisc.ernet.in/id/eprint/33780

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