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Structure of the rhenium X-ray LIII absorption edge in caesium hexachlororhenate(IV)

Sarode, PR (1979) Structure of the rhenium X-ray LIII absorption edge in caesium hexachlororhenate(IV). In: Dalton Transactions (6). pp. 993-995.

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1979...

Abstract

The X-ray LIII absorption-edge structure of rhenium in Cs2[ReCl6] has been measured with a bent-crystal X-ray spectrograph. An analysis in terms of molecular-orbital (m.o.) theory has been attempted. The energies of the m.o. levels, crystal-field splitting parameter, effective magnetic moment, magnetic susceptibility, and Landég parameter have been determined from this analysis. An estimate of the Re–Cl bond length has also been made.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 28 Dec 2010 06:42
Last Modified: 28 Dec 2010 06:42
URI: http://eprints.iisc.ernet.in/id/eprint/33930

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