Sengupta, Debasis and Sumathi, R and Chandra, AK (1991) Role of barriers to conformational changes in ketones undergoing the Norrish type II process. In: Journal of Photochemistry and Photobiology A: Chemistry, 60 (2). 149 -159.
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Abstract
The Norrish type II process is examined in three ketones containing primary, secondary and tertiary C---H bonds in the γ position relative to the carbonyl groups; the MINDO/3 semiempirical self-consistent field (SCF) molecular orbital (MO) method was used with complete geometry optimization in the unrestricted Hartree—Fock frame for the open-shell species. Results show that barriers to conformational change in ketones play an important role in the triplet reaction.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier science. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 30 Nov 2010 06:10 |
| Last Modified: | 30 Nov 2010 06:10 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/34119 |
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