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Role of barriers to conformational changes in ketones undergoing the Norrish type II process

Sengupta, Debasis and Sumathi, R and Chandra, AK (1991) Role of barriers to conformational changes in ketones undergoing the Norrish type II process. In: Journal of Photochemistry and Photobiology A: Chemistry, 60 (2). 149 -159.

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Official URL: http://dx.doi.org/10.1016/1010-6030(91)85055-L

Abstract

The Norrish type II process is examined in three ketones containing primary, secondary and tertiary C---H bonds in the γ position relative to the carbonyl groups; the MINDO/3 semiempirical self-consistent field (SCF) molecular orbital (MO) method was used with complete geometry optimization in the unrestricted Hartree—Fock frame for the open-shell species. Results show that barriers to conformational change in ketones play an important role in the triplet reaction.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 30 Nov 2010 06:10
Last Modified: 30 Nov 2010 06:10
URI: http://eprints.iisc.ernet.in/id/eprint/34119

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