ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Deviation from Arrhenius behaviour of rate of intercage diffusion in Zeolite $Y^{1}$

Santikary, Prakriteswar and Yashonath, Subramanian (1996) Deviation from Arrhenius behaviour of rate of intercage diffusion in Zeolite $Y^{1}$. In: Electronic Journal of Theoretical Chemistry, 1 . pp. 87-92.

[img] PDF
page9au.pdf

Download (187Kb)

Abstract

Rate of intercage diffusion (kc) along with rate of cage visits (kv) and diffusion coefficient (D) of sorbates in zeolite Y have been calculated. We show that as a consequence of the dependence of rate of intercage diffusion on short-time behaviour, significant deviation from the Arrhenius behaviour at suffciently high temperatures occurs.

Item Type: Journal Article
Additional Information: The copyright belongs to John Wiley & Sons, Ltd.The DOI is currently only displayed.
Keywords: diffusion;arrhenius law;zeolite y;molecular dynamics
Department/Centre: Division of Information Sciences > Supercomputer Education & Research Centre
Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 27 Jul 2005
Last Modified: 19 Sep 2010 04:19
URI: http://eprints.iisc.ernet.in/id/eprint/3418

Actions (login required)

View Item View Item