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Synthesis Based On Cyclohexadienes .6. A New Total Synthesis Of (+/-)-Methyl Acorate And (+/-)-Methyl Epi-Acorate

Ramanathan, H and Rao, GSRS (1991) Synthesis Based On Cyclohexadienes .6. A New Total Synthesis Of (+/-)-Methyl Acorate And (+/-)-Methyl Epi-Acorate. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 30 (10). pp. 901-910.

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Official URL: http://www.niscair.res.in/ScienceCommunication/Res...

Abstract

A new method of construction of carbon-carbon bond is described. Thus the dianions generated from the metal-ammonia reduction of substituted benzoic acids readily undergo Michael addition with methyl crotonate resulting in synthetically useful products having a quaternary carbon. Based on this strategy, new syntheses of (+/-)-methyl acorate (14b) and (+/-)-methyl epi-corate (15) are reported.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 07 Dec 2010 09:47
Last Modified: 07 Dec 2010 09:47
URI: http://eprints.iisc.ernet.in/id/eprint/34189

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