Ramanathan, H and Rao, GSRS (1991) Synthesis Based On Cyclohexadienes .6. A New Total Synthesis Of (+/-)-Methyl Acorate And (+/-)-Methyl Epi-Acorate. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 30 (10). pp. 901-910.Full text not available from this repository.
A new method of construction of carbon-carbon bond is described. Thus the dianions generated from the metal-ammonia reduction of substituted benzoic acids readily undergo Michael addition with methyl crotonate resulting in synthetically useful products having a quaternary carbon. Based on this strategy, new syntheses of (+/-)-methyl acorate (14b) and (+/-)-methyl epi-corate (15) are reported.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to National Institute of Science Communication and Information Resources.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||07 Dec 2010 09:47|
|Last Modified:||07 Dec 2010 09:47|
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