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Synthesis, Characterization and Structure of (N2H5)3MnX5 (X = Cl and Br)

Kumar , Sreenivasa KR and Nethaji , M and Patil, KC (1991) Synthesis, Characterization and Structure of (N2H5)3MnX5 (X = Cl and Br). In: Journal of Coordination Chemistry, 24 (4). 333 -337.

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Abstract

Two new hydrazinium complexes of manganese, (N2H5)3MnX5 (X = Cl and Br), have been prepared and characterized by analysis, infrared and visible spectra. The single crystal X-ray structure of the chloride complex has been determined. Only one of the three N2H+5 cations is coordinated to the metal. In the anion, [Mn(N2H5)Cl5]2-, the coordination polyhedron around the manganese atom is a slightly distorted octahedron.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Keywords: Hydrazinium cation;manganese complex;X-ray structure.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 14 Dec 2010 05:30
Last Modified: 14 Dec 2010 05:30
URI: http://eprints.iisc.ernet.in/id/eprint/34192

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