Patil, KC and Soundararajan, R and Verneker, Pai VR (1979) Preparation and characterization of hydrazine derivatives. Part-II: Reaction of transition metal ammonium double sulphates with hydrazine hydrate. In: Proceedings of the Indian Academy of Sciences - Section A, 88 (3). pp. 211-216.
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Abstract
Transition metal ammonium double sulphates (NH4)2M(SO4)2· 6H2O, where M = Fe, Co and Ni react with hydrazine hydrate in air giving crystalline compounds of the general formula (N2H5) [M(N2H3COO)3] H2O. The reaction proceeds through (N2H5)2 M(SO4)2, · 3N2H4, (N2H5)2 [M(OH)4 · (N2H4)2], M(N2H3COO)2 · (N2H4)2 and N2H5 [M(N2 H3 COO)3] intermediates. The reaction sequence is followed by chemical analysis and infrared spectra. A possible reaction mechanism has been suggested.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Hydrazine derivatives;hydrazido carbonates . |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry Others |
| Date Deposited: | 27 Dec 2010 10:48 |
| Last Modified: | 27 Dec 2010 10:48 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/34204 |
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