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Preparation and characterization of hydrazine derivatives. Part-II: Reaction of transition metal ammonium double sulphates with hydrazine hydrate

Patil, KC and Soundararajan, R and Verneker, Pai VR (1979) Preparation and characterization of hydrazine derivatives. Part-II: Reaction of transition metal ammonium double sulphates with hydrazine hydrate. In: Proceedings of the Indian Academy of Sciences - Section A, 88 (3). pp. 211-216.

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Abstract

Transition metal ammonium double sulphates (NH4)2M(SO4)2· 6H2O, where M = Fe, Co and Ni react with hydrazine hydrate in air giving crystalline compounds of the general formula (N2H5) [M(N2H3COO)3] H2O. The reaction proceeds through (N2H5)2 M(SO4)2, · 3N2H4, (N2H5)2 [M(OH)4 · (N2H4)2], M(N2H3COO)2 · (N2H4)2 and N2H5 [M(N2 H3 COO)3] intermediates. The reaction sequence is followed by chemical analysis and infrared spectra. A possible reaction mechanism has been suggested.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Keywords: Hydrazine derivatives;hydrazido carbonates .
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Others
Date Deposited: 27 Dec 2010 10:48
Last Modified: 27 Dec 2010 10:48
URI: http://eprints.iisc.ernet.in/id/eprint/34204

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