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The first structurally characterized diruthenium(II,III) complex with four bridging arylcarboxylato ligands

Das, Birinchi K and Chakravarty, Akhil R (1991) The first structurally characterized diruthenium(II,III) complex with four bridging arylcarboxylato ligands. In: Polyhedron, 10 (4-5). pp. 491-494.

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Official URL: http://dx.doi.org/10.1016/S0277-5387(00)80218-1

Abstract

The diruthenium(II,III) compound [Ru2Cl(O2CC6H4-p-OMe)4](H2O)0.25 (1) has been prepared and its crystal structure determined by X-ray studies. The crystals belong to the triclinic space group, PImage , and the asymmetric unit consists of one full dimer and two half dimers. The {Ru2(O2CC6H4-p-OMe)4+} units are bridged by chloride ions into an infinite zigzag chain, with an average Ru---Cl distance and Ru---Cl---Ru angle of 2.567(2) Å and 121.0(1)°, respectively. The average Ru---Ru distance of 2.286(1) Å in 1 is comparable with that in analogous tetra-alkylcarboxylates, Ru2Cl(O2CR)4 and tetra-amidates, Ru2Cl(ArCONH)4.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier science.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 14 Dec 2010 04:52
Last Modified: 14 Dec 2010 04:52
URI: http://eprints.iisc.ernet.in/id/eprint/34231

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