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Crystal and Molecular Structure of N-acetyl-L-glutamine

Murthy, MRN and Venkatesan, Kailasam and Winkler, Fritz (1976) Crystal and Molecular Structure of N-acetyl-L-glutamine. In: Journal of the Chemical Society, Perkin Transactions 2 (6). 768-771 .

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Abstract

The crystal and molecular structure of the title compound has been determined by direct methods from diffractometer data. Crystals are orthorhombic, with Z= 4 in a unit cell of dimensions : a= 13.811 (10), b= 5.095(5), c= 12.914(10)Å, space group P212121. The structure was refined by least-squares to R 3.31% for 868 observed reflections. There is significant non-planarity of the peptide group and its nitrogen atom is significantly pyramidal. There is no correlation between the double-bond character and reactivity of the C–N bond of the terminal amide group in glutamine and acetamide

Item Type: Journal Article
Additional Information: Copyright of this article e belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 Dec 2010 06:12
Last Modified: 14 Dec 2010 06:12
URI: http://eprints.iisc.ernet.in/id/eprint/34298

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