Srikanth, S and Jacob, KT (1991) Vapor-Pressure Of Calcium Corresponding To The Reduction Of Calcia By Aluminum. In: Transactions of the Indian Institute of Metals, 44 (5). 369 -373.
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The equilibrium pressure of calcium corresponding to the reduction reaction 6CaO (s) + 2Al (l) half-arrow-right-over-half-arrow-left 3CaO.Al2O3 (s) + 3Ca (g) has been measured by Knudsen effusion - mass loss analysis in the temperature range 1190 - 1500 K. The measured vapour pressure can be expressed as a function of temperature by the relation: log p(Ca) (Pa) = -10,670/T + 9.267 The calcium generated is partially absorbed by aluminium to form an alloy. The equilibrium composition of the alloy at 1373 K was found to be 22 mol% Ca - 78 mol% Al. The measured vapour pressure is in good agreement with that computed from thermodynamic data.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Indian Inst Metals.|
|Department/Centre:||Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)|
|Date Deposited:||07 Dec 2010 06:52|
|Last Modified:||09 Dec 2011 09:29|
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