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Infrared and Nuclear Quadrupole Resonance Studies of the Phase Transitions of Para-dichlorobenzene

Ganguly, S and Fernandes, JR and Bahadur, D and Rao, CNR (1979) Infrared and Nuclear Quadrupole Resonance Studies of the Phase Transitions of Para-dichlorobenzene. In: Faraday Transactions 2, 75 (Part 6). pp. 923-928.

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Abstract

The α→γ→α→β transitions of para-dichlorobenzene have been studied by employing infrared and n.q.r. spectroscopy as well as differential scanning calorimetry. The γ phase is associated with considerably higher values of some of the intramolecular vibration frequencies. The α→γ transition shows athermal nucleation behaviour as in martensitic transitions. Intermolecular vibration bands around 46 and 85 cm–1 present in γ and α phases disappear in the β phase. The α→β transition seems to be associated with some orientational disorder.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 23 Dec 2010 06:17
Last Modified: 23 Dec 2010 06:17
URI: http://eprints.iisc.ernet.in/id/eprint/34377

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